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Abstract We used new high spectral resolution observations of propynal (HCCCHO) toward TMC-1 and in the laboratory to update the spectral line catalog available for transitions of HCCCHO—specifically at frequencies lower than 30 GHz, which were previously discrepant in a publicly available catalog. The observed astronomical frequencies provided a high enough spectral resolution that, when combined with high-resolution (∼2 kHz) measurements taken in the laboratory, a new, consistent fit to both the laboratory and astronomical data was achieved. Now with a nearly exact (<1 kHz) frequency match to theJ= 2–1 and 3–2 transitions in the astronomical data, using a Markov Chain Monte Carlo analysis, a best fit to the total HCCCHO column density of ${7.28}_{-1.94}^{+4.08}\times {10}^{12}$cm⁻²was found with a surprisingly low excitation temperature of just over 3 K. This column density is around a factor of 5 times larger than reported in previous studies. Finally, this work highlights that care is needed when using publicly available spectral catalogs to characterize astronomical spectra. The availability of these catalogs is essential to the success of modern astronomical facilities and will only become more important as the next generation of facilities comes online. 

Polycyclic aromatic hydrocarbons (PAHs) are organic molecules containing adjacent aromatic rings. Infrared emission bands show that PAHs are abundant in space, but only a few specific PAHs have been detected in the interstellar medium. We detected 1-cyanopyrene, a cyano-substituted derivative of the related four-ring PAH pyrene, in radio observations of the dense cloud TMC-1, using the Green Bank Telescope. The measured column density of 1-cyanopyrene is $\sim \text{1}{\text{.52×10}}^{\text{12}}$cm⁻², from which we estimate that pyrene contains up to 0.1% of the carbon in TMC-1. This abundance indicates that interstellar PAH chemistry favors the production of pyrene. We suggest that some of the carbon supplied to young planetary systems is carried by PAHs that originate in cold molecular clouds.